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無機(jī)化學(xué)

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無機(jī)化學(xué)

高山

發(fā)布時(shí)間:2015-06-05 作者: 瀏覽量:

高山,男,,教授,、博士生導(dǎo)師,。1966年7月出生。1985年-1992年就讀于黑龍江大學(xué)化學(xué)系,,并先后獲得理學(xué)學(xué)士和理學(xué)碩士學(xué)位,,1992~1994年在哈爾濱工業(yè)大學(xué)化學(xué)系無機(jī)教研室任教,1998年獲得福州大學(xué)化學(xué)系物理化學(xué)專業(yè)博士學(xué)位,,隨后在吉林大學(xué)無機(jī)合成與制備化學(xué)國家重點(diǎn)實(shí)驗(yàn)室從事博士后研究工作,。1999年至今在黑龍江大學(xué)化學(xué)化工與材料學(xué)院任教。目前涉及的主要研究領(lǐng)域?yàn)楣δ芘湮徊牧吓c納米功能材料,。作為主持人和主要參與人完成國家和省級(jí)基金等項(xiàng)目十余項(xiàng),,在研國家級(jí)和部級(jí)項(xiàng)目?jī)身?xiàng)。近年來,,以通訊作者身份在國內(nèi)外學(xué)術(shù)刊物J. Mater. Chem. A, J. Hazard. Mater., Sensor Actuat B, Inorg. Chem., Cryst. Growth & Des., Front. Chem., Organometallics, Dalton Trans., CystEngComm, RSC Adv., Eur. J. Inorg. Chem., Mater. Lett., J. Solid State Chem., Tetrahedron等國際期刊上發(fā)表SCI論文百余篇,,其中影響因子大于3.0的文章30余篇,總計(jì)被他人正面引用600余次,。獲得授權(quán)專利6項(xiàng),,通過黑龍江省科技廳鑒定成果一項(xiàng)(國際先進(jìn))。獲省科技進(jìn)步二等獎(jiǎng)兩項(xiàng),,省高??萍歼M(jìn)步一等獎(jiǎng)一項(xiàng)和二等獎(jiǎng)兩項(xiàng)。現(xiàn)為中國化學(xué)會(huì)會(huì)員和中國晶體學(xué)會(huì)員,,并擔(dān)任國際和國內(nèi)某些知名SCI期刊的通訊評(píng)審人,。

Email[email protected]

學(xué)科專業(yè):無機(jī)化學(xué)

研究領(lǐng)域:功能配位材料與納米功能材料

主要研究方向:

1.納米孔金屬有機(jī)晶態(tài)網(wǎng)絡(luò)的設(shè)計(jì)合成與功能化。

2.水溶性金屬有機(jī)晶態(tài)網(wǎng)絡(luò)的設(shè)計(jì)合成與發(fā)光性能,。

3.有機(jī)超分子晶態(tài)網(wǎng)絡(luò)(藥物共晶化合物)的組裝與表征,。

4.多級(jí)結(jié)構(gòu)微納米氧化物的建構(gòu)與敏感,、儲(chǔ)鋰等性能研究,。

代表性論文

  1. Ting-Ting Xu, Xian-Fa Zhang, Xin Dong, Zhao-Peng Deng*, Li-Hua Huo, Shan Gao*, Enhanced H2S gas-sensing performance of Zn2SnO4hierarchical quasimicrospheres constructed from nanosheets and octahedra,J. Hazard. Mater.,2019,361, 49-55.

  2. Ting-Ting Xu, Ying-Ming Xu, Xian-Fa Zhang, Zhao-Peng Deng*, Li-Hua Huo and Shan Gao*, Enhanced H2S Gas-SensingPerformance of Zn2SnO4Lamellar Micro-Spheres,Front. Chem.,2018, doi: 10.3389/fchem.2018.00165.

  3. Zhong-Yi Ge, Zhi-Biao Zhu, Zhao-Peng Deng,* Li-Hua Huo and Shan Gao*, Structure evolution and luminescence properties of lithium(I)-sulfonate complexes constructed from multifunctional arenedisulfonic acids,CrystEngComm,2018,20, 2968-2979.

  4. Guo-Zhen Huang, Xin Zou, Zhi-Biao Zhu, Zhao-Peng Deng*, Li-Hua Huo, Shan Gao*, Syntheses and characterizations of secondary Pb-O bonding supported Pb(II)-sulfonate complexes,J. Solid State Chem.,2018, 262, 214-223.

  5. Meng Zhang, Xian-Fa Zhang, Zhao-Peng Deng*, Li-Hua Huo, Shan Gao*, Synthesis and characterization of novel hierarchical metal oxide using scallion root as biotemplate,Mater. Lett.,2018,223, 61-64.

  6. Ying-Hui Xiao, Zhao-Peng Deng*, Zhi-Biao Zhu, Li-Hua Huo and Shan Gao*, Rare earth metal–organic complexes constructed from hydroxyl and carboxyl modified arenesulfonate: syntheses, structure evolutions, and ultraviolet, visible and near-infrared luminescence,Dalton Trans.,2017,46, 16493-16504.

  7. Fa-Yuan Ge, Xin Ma, Dan-Dan Guo, Li-Na Zhu, Zhao-Peng Deng,* Li-Hua Huo, and Shan Gao*, Syntheses, Structural Evolutions, and Properties of Cd(II) Coordination Polymers Induced by Bis(pyridyl) Ligand with Chelated or Protonated Spacer and Diverse Counteranions,Cryst. Growth Des.,2017,17,2667?2681.

  8. Guo-Zhen Huang, Xin Zou, Zhi-Biao Zhu, Zhao-Peng Deng,* Li-Hua Huo and Shan Gao*, Effect of ligand configurations, secondary Pb-O interactions and auxiliary ligands on Pb(II)-mono/disulfonate complexes: synthesis, structures, and luminescent properties,CrystEngComm,2017,19, 1778-1791.

  9. Ying-Hui Xiao, Jing Huang, Zhao-Peng Deng*, Li-Hua Huo, Shan Gao*, Syntheses and characterizations of multinuclear, chain and layer silver(I) complexes assembled from bispyridine analogues of pyridinyl-hexahydropyrimidine,J. Solid State Chem.,2017, 251, 255-265.

  10. Zheng-Yang Ye, Zhu-Yan Zhang, Li-Hua Huo, Zhao-Peng Deng*, Xian-Fa Zhang,Shan Gao*, Mercury supramolecular architectures constructed from flexibleunsymmetrical bis(pyridyl) ligands: Structural motif mediated bymercury-halide clusters, ligand conformations and non-covalent interactions,Polyhedron,2016,117,338-351.

  11. Ya-Nan Li, Li-Hua Huo, Xin Zou,Zhao-Peng Deng,* Zhi-Biao Zhu andShan Gao*, Chiral supramolecular compounds comprising naphthalene-1,5-disulfonic acid and various a-amino acids: influence of substituents ofα-amino acids on the structures, circular dichroism and luminescent properties,Tetrahedron,2015,71, 8746-8757.

  12. Jing Huang,Zhao-Peng Deng,Ying-Hui Xiao, Li-Hua Huo,* Shu-Nan Zhao, Fa-Yuan Ge andShan Gao*, Macrocyclic dinuclear, helical, layered and 3-D Ag(I) complexes constructed from AgX (X = NO3?and ClO4?) and flexible bis(pyridyl) ligands with a chelating spacer: syntheses, structures and photoluminescence properties,Dalton Trans.,2015,44, 5837-5847.

  13. Ya-Nan Li, Li-Hua Huo,Zhao-Peng Deng,* Xin-Yu Xie, Zhi-Biao Zhu andShan Gao*, Nature of reactant and influence of water on the supramolecular patterns and luminescent properties of organic salts comprising (1,1’-biphenyl)- 4,4’-disulfonate and triphenylmethanaminium,RSC Adv.,2015,5, 41692-41706.

  14. Yi-Zhe Yu, Ya-Nan Li,Zhao-Peng Deng,* Zhi-Biao Zhu, Li-Hua Huo, andShan Gao*, Influence of Metal Cations and Coordination Modes on Luminescent Group 1 and 2 Metal Sulfonate Complexes Constructed from 4,4’-Dihydroxybiphenyl- 3,3’-disulfonic Acid,Eur. J. Inorg. Chem.,2015, 2254-2263.

  15. Ya-Nan Li, Li-Hua Huo,Zhao-Peng Deng,* Xin Zou, Zhi-Biao Zhu, Hui Zhao, andShan Gao*, Solvent Effect on the Supramolecular Patterns and Luminescent Properties of Organic Salts Comprising Naphthalene-1,5-disulfonic Acid and Triphenylmethylamine,Cryst. Growth Des.,2014,14, 2381?2393.

  16. Zhu-Yan Zhang,Zhao-Peng Deng, Xian-Fa Zhang, Li-Hua Huo,* Hui Zhao andShan Gao*, Self-assembly of [Cu3I2]- or [CuI]n-based (n = 2, 4, and∞) coordination polymers from unsymmetrical bis(pyridyl) and in situ ligands: syntheses, structures, and properties,CrystEngComm,2014,16, 359-368.

  17. Tong-Peng Liu, Li-Hua Huo,Zhao-Peng Deng,* Hui Zhao andShan Gao*, Supramolecular architectures and luminescent properties of the salts containing flexible bis(pyridyl) cations with aliphatic diamine spacer: effects of inorganic anions, alkalinity and conformation of the bis(pyridyl) cations,RSC Adv.,2014,4, 40693-40710.

  18. Ya-Nan Li, Li-Hua Huo, Yi-Zhe Yu, Fa-Yuan Ge,Zhao-Peng Deng,* Zhi-Biao Zhu andShan Gao*, Influence of solvents and assembly methods on the supramolecular patterns and luminescent properties of organic salts comprising 4,4’- dihydroxybiphenyl-3,3’-disulfonate and triphenylmethanaminium,RSC Adv.,2014,4, 64802-64815.

  19. Zhu-Yan Zhang,Zhao-Peng Deng, Li-Hua Huo,* Hui Zhao andShan Gao*, Well-Designed Strategy To Construct Helical Silver(I) Coordination Polymers from Flexible Unsymmetrical Bis(pyridyl) Ligands:Syntheses, Structures, and Properties,Inorg. Chem.,2013,52, 5914-5923.

  20. Zhu-Yan Zhang,Zhao-Peng Deng, Li-Hua Huo,* Hui Zhao andShan Gao*, Inorganic anion induced supramolecular architectures of flexible unsymmetrical bis(pyridyl) ionic salts mediated by various non-covalent interactions,CrystEngComm,2013,15, 5261-5274.

  21. Zhao-Peng Deng, Li-Hua Huo*, Hui Zhao,Shan Gao*, A strategy to tune the supramolecular patterns and luminescent properties: ten well-designed cocrystals assembled by arenedisulfonic acid with diverse diamines,Cryst. Growth Des.,2012,12, 3342-3355.

  22. Zhao-Peng Deng, Wei Kang, Zhi-Biao Zhu, Li-Hua Huo*, Hui Zhao,Shan Gao*, Cation radii induced structural variation in fluorescent alkaline earth networks constructed from tautomers of a nucleobase analogue,Dalton Trans.,2012,41, 8354-8360.

  23. Zhao-Peng Deng, Zhu-Yan Zhang, Li-Hua Huo*, Seik-Weng Ng, Hui Zhao,Shan Gao*, Syntheses, crystal structures and properties of transition metal coordination polymers based on isophthalic acid and flexible bis(pyridyl) ligand with unsymmetrical spacer: influence of metal cations, ligand conformations and coordination modes,CrystEngComm,2012,14, 6548-6558.

  24. Wang Wan, Zhi-Biao Zhu, Li-Hua Huo,Zhao-Peng Deng*, Hui Zhao,Shan Gao*, Syntheses, structures and luminescent properties of lithium(I)-sulfonate complexes constructed from ortho-hydroxyl arenedisulfonic acids: structural evolution tuned by the pH, coordination geometry and modes,CrystEngComm,2012,14, 5274-5284.

  25. Huang Wang, Li-Hua Huo,Zhao-Peng Deng*, Hui Zhao,Shan Gao*, Syntheses, crystal structures and luminescent properties of Zn(II)/Cd(II) supramolecular complexes incorporating 4-sulfinobenzoate and its in situ oxidized ligand,CrystEngComm,2012,14, 3501-3508.

  26. Zhi-Biao Zhu, Wang Wan,Zhao-Peng Deng, Zhong-Yi Ge, Li-Hua Huo*, Hui Zhao,Shan Gao*, Structure modulations in luminescent alkaline earth metal-sulfonate complexes constructed from dihydroxyl-1,5-benzenedisulfonic acid: Influences of metal cations, coordination modes and pH value,CrystEngComm,2012,14, 6675-6688.

  27. Xian-Fa Zhang,Zhao-Peng Deng, Li-Hua Huo*, Qing-Mao Feng,Shan Gao*, Four alkali-Induced 3D strontium(II) coordination polymers constructed from imidazole-4,5-dicarboxylate: syntheses, crystal structures, and properties,Eur. J. Inorg. Chem.,2012, 5506-5514.

  28. Zhao-Peng Deng, Li-Hua Huo, Ming-Shuai Li, Li-Wei Zhang, Zhi-Biao Zhu*, Hui Zhao,Shan Gao*, Syntheses, Structures, and Luminescent Properties of Silver(I) Complexes Constructed fromortho-Hydroxyl Arenesulfonic Acids,Cryst. Growth Des.,2011,11, 3090-3100.

  29. Xiang-Qian Fang,Zhao-Peng Deng, Li-Hua Huo*, Wang Wan, Zhi-Biao Zhu, Hui Zhao,Shan Gao*, New Family of Silver(I) Complexes Based on Hydroxyl and Carboxyl Groups Decorated Arenesulfonic Acid: Syntheses, Structures, and Luminescent Properties,Inorg. Chem.,2011,50, 12562-12574.

  30. Zhao-Peng Deng, Ming-Shuai Li, Zhi-Biao Zhu, Li-Hua Huo*, Hui Zhao,Shan Gao*, Rare Organosilver(I) Coordination Polymers Constructed from Hydroxyl-Substituted Benzenesulfonic Acids: Syntheses, Structures and Characterizations,Organometallics,2011,30, 1961-1967.

  31. Zhao-Peng Deng, Zhi-Biao Zhu, Xian-Fa Zhang, Li-Hua Huo*, Hui Zhao,Shan Gao*, The first in situ organosulfonate-templated 3-fold interpenetrating framework built from rare tetrahedral [Cu4(μ4-SO4)] SBUs,CrystEngComm,2011,13, 3895-3899.

  32. Zhao-Peng Deng, Li-Hua Huo*, Hui Xu, Hui Zhao,Shan Gao*, The first metal–organic framework containing an unprecedented in situ-generated C-substituted hexamethylenetetramine ligand,Dalton Trans.,2011,40, 1224-1226.

  33. Zhao-Peng Deng, Hui-Ling Qi, Li-Hua Huo*, Hui Zhao,Shan Gao*, Inorganic anion induced supramolecular architectures and luminescent properties of flexible bis(pyridyl) based ionic salts,CrystEngComm,2011,13, 6632-6642.

  34. Zhao-Peng Deng, Li-Hua Huo, Hui-Ling Qi, Li-Na Zhu, Hui Zhao,Shan Gao*, Structural diversity of Zn(II)/Cd(II) complexes based on bis(pyridyl) ligands with a long flexible spacer: From zero-dimensional binuclear, one-dimensional chain, two-dimensional layer, to three-dimensional frameworks,CrystEngComm,2011,13, 4218-4227.

  35. Zhao-Peng Deng, Li-Hua Huo, Huan-Yu Wang,Shan Gao*, Hui Zhao, A series of three-dimensional lanthanide metal–organic frameworks with biphenylethene-4,4’-dicarboxylic acid: Hydrothermal syntheses and structures,CrystEngComm,2010,12, 1526-1535.

  36. Zhao-Peng Deng, Wei Kang, Li-Hua Huo, Hui Zhao,Shan Gao*, Rare-earth organic frameworks involving three types of architecture tuned by the lanthanide contraction effect: hydrothermal syntheses, structures and luminescence,Dalton Trans.,2010,39, 6276-6284.

  37. Zhao-Peng Deng, Hui-Ling Qi, Li-Hua Huo,* Seik Weng Ng, Hui Zhao andShan Gao*,Syntheses and structures of copper(I) complexes based on CunXn (X = Br and I; n = 1, 2 and 4) units and bis(pyridyl) ligands with longer flexible spacer,Dalton Trans.,2010,39, 10038-10050.

  38. Zhao-Peng Deng, Zhi-Biao Zhu,Shan Gao*, Li-Hua Huo, Hui Zhao, Seik Weng Ng, A series of silver(I) pyridone-sulfonates with 1-D“butterfly”chain, 2-D lamellar network and 3-D pillared layered frameworks: syntheses, structures and characterizations,Dalton Trans.,2009, 6552-6561.

  39. Zhao-Peng Deng, Zhi-Biao Zhu,Shan Gao*, Li-Hua Huo, Hui Zhao, The first continuous silver polyhedra framework containing four kinds of coordination spheres,Dalton Trans.,2009, 1290-1292.

  40. Zhao-Peng Deng, Li-Na Zhu,Shan Gao*, Li-Hua Huo, Seik Weng Ng, Self-Assembly of Discrete Metallocycle versus Coordination Polymer Based on Silver(I) and Di-2- and Di-3-pyridines with Flexible Spacer,Crystal Growth Des.,2008,8, 3277-3284.

授權(quán)專利:

1.霍麗華,P·蘇曼,,趙輝,,高山,程曉麗.敏感材料及用敏感材料制成的甲醛敏感元件及敏感元件的制作方法,,ZL200710071884.X(2010)

2.霍麗華,,楊銘,趙輝,,高山,,程曉麗.一種丙酮?dú)饷舨牧霞捌鋺?yīng)用.ZL200710144666.4(2010)

3.程曉麗,霍麗華,,徐英明,,高山,,趙輝,由三種維度單元構(gòu)建的多級(jí)結(jié)構(gòu)氧化鋅及其制備方法,,ZL201010120106.7(2011)

4.徐英明,,霍麗華,馬驊,,程曉麗,,高山,趙輝,,類立方體納米單元構(gòu)筑的尺寸可控的單分散氧化鉻多孔微球及其制備方法,,2013.12,中國發(fā)明專利,ZL201210096028.0

5.程曉麗;霍麗華;宋肖肖;徐英明;張現(xiàn)發(fā);高山;趙輝,,多級(jí)結(jié)構(gòu)花狀二氧化鉬的制備方法,,2014.,7,中國發(fā)明專利,,ZL201210417187.6

6.程曉麗;霍麗華;宋肖肖;徐英明;張現(xiàn)發(fā);高山;趙輝,,一種二氧化鉬核殼微球的制備方法,2014.,7,,中國發(fā)明專利,,ZL201210417156.0

主要獲獎(jiǎng):

1.霍麗華,高山,,趙輝,,徐英明,程曉麗,,氧化物基納米材料的組裝與氣敏性質(zhì)研究,,黑龍江省高校科學(xué)技術(shù)獎(jiǎng)一等獎(jiǎng),,2011.03

2.趙輝,,霍麗華,高山,,李強(qiáng),,孫麗萍.納米氧化物材料的軟化學(xué)合成及性質(zhì)研究.黑龍江省科學(xué)技術(shù)二等獎(jiǎng),2008.06

3.霍麗華,,高山,,趙經(jīng)貴,蔡莊,,程曉麗.納米氧化物及其雜化薄膜的組裝與性能研究.黑龍江省科學(xué)技術(shù)二等獎(jiǎng),,2003.08

主要在研項(xiàng)目:

1.黑龍江省自然科學(xué)基金面上項(xiàng)目,B2015007,《基于芳香磺酸建構(gòu)的熒光超分子晶態(tài)網(wǎng)絡(luò)材料的設(shè)計(jì)與調(diào)控》,2015.07-2018.07,,第二,。

2.國家自然科學(xué)基金,51302067,《光功能芳香磺酸晶態(tài)網(wǎng)絡(luò)材料的設(shè)計(jì)與合成》,,2014.01-2016.12,,第二。

代表性結(jié)題項(xiàng)目:

1.黑龍江省自然科學(xué)基金重點(diǎn)項(xiàng)目,,ZD200903,《新型納米多孔配位聚合物材料的組裝與性能研究》,,2010.01-2012.12,主持,。

2.黑龍江省教育廳科學(xué)技術(shù)研究重點(diǎn)項(xiàng)目,,12511Z023,《具有納米孔金屬有機(jī)分子篩材料的構(gòu)筑與性能研究》2011.01-2013.12,主持,。